The dynamics of elementary processes and combustion kinetics

R. D. Levine

doi:10.1016/0010-2180(89)90004-7

The dynamics of elementary processes and combustion kinetics

R. D. Levine^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The relevance of both experimental and theoretical studies of the dynamics of elementary reactions towards the understanding of combustion and flames is emphasized with examples. An overview considers in particular the importance of thermal disequilibrium and of three-body effects which we suggest are more common than often considered. As a specific problem, the extrapolation of the reaction rate constant to higher temperatures is considered. The increase of the activation energy with temperature is dicussed in general and the particular reasons why it so increases for the H + H₂ reaction are examined in some detail.

Original language	English
Pages (from-to)	5-11
Number of pages	7
Journal	Combustion and Flame
Volume	78
Issue number	1
DOIs	https://doi.org/10.1016/0010-2180(89)90004-7
State	Published - Oct 1989

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The dynamics of elementary processes and combustion kinetics

Abstract

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