The geometrical-classical limit of algebraic Hamiltonians for molecular vibrotational spectra

O. S. van Roosmalen*, R. D. Levine, A. E.L. Dieperink

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

76 Scopus citations

Abstract

A classical limit, which is amenable to a geometrical interpretation, is discussed for the vibron model of molecular vibrotational spectra. Both diatomic and triatomic molecules are considered. An example of a coupling between the two stretching modes of a linear triatomic is examined in detail.

Original languageEnglish
Pages (from-to)512-517
Number of pages6
JournalChemical Physics Letters
Volume101
Issue number6
DOIs
StatePublished - 4 Nov 1983

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