Abstract
Refined variational calculations of the first- and second-order hyperfine interaction coefficients d1 and d2 have been performed for the hydrogen-molecule-ion. The electronic matrix elements were carefully stabilized for each coefficient separately and the vibration-rotation wavefunctions calculated from a nuclear potential which yields correct dissociation limits. The resulting values are in good agreement with earlier theoretical and experimental determinations for the N = 2 nuclear rotational levels, and are in impressive agreement with measurements of the N = 1 rotational levels.
Original language | English |
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Pages (from-to) | 374-378 |
Number of pages | 5 |
Journal | Chemical Physics Letters |
Volume | 49 |
Issue number | 2 |
DOIs | |
State | Published - 15 Jul 1977 |