The interaction of lanthanide and nitrate ions in solution - II. The relative interaction strength with water and nitrate in organic solvents

I. Abrahamer; Y. Marcus

doi:10.1016/0022-1902(68)80296-9

The interaction of lanthanide and nitrate ions in solution - II. The relative interaction strength with water and nitrate in organic solvents

I. Abrahamer^*, Y. Marcus

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

The competition of water, nitrate ions and solvent for interaction with lanthanide ions has been studied by measuring the absorption spectra of solutions containing suitable combinations of these components. The role of the water in lanthanide nitrate extracts by TBP and by a tri-alkylammonium nitrate solution has also been studied. The following affinity series of ligands and solvents for lanthanide ions has been obtained: DMF>TBP >NO₃-∼H₂O >EtOH >dioxane.

Original language	English
Pages (from-to)	1563-1575
Number of pages	13
Journal	Journal of Inorganic and Nuclear Chemistry
Volume	30
Issue number	6
DOIs	https://doi.org/10.1016/0022-1902(68)80296-9
State	Published - Jul 1968
Externally published	Yes

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title = "The interaction of lanthanide and nitrate ions in solution - II. The relative interaction strength with water and nitrate in organic solvents",

abstract = "The competition of water, nitrate ions and solvent for interaction with lanthanide ions has been studied by measuring the absorption spectra of solutions containing suitable combinations of these components. The role of the water in lanthanide nitrate extracts by TBP and by a tri-alkylammonium nitrate solution has also been studied. The following affinity series of ligands and solvents for lanthanide ions has been obtained: DMF>TBP >NO3-∼H2O >EtOH >dioxane.",

author = "I. Abrahamer and Y. Marcus",

year = "1968",

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AU - Abrahamer, I.

AU - Marcus, Y.

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AB - The competition of water, nitrate ions and solvent for interaction with lanthanide ions has been studied by measuring the absorption spectra of solutions containing suitable combinations of these components. The role of the water in lanthanide nitrate extracts by TBP and by a tri-alkylammonium nitrate solution has also been studied. The following affinity series of ligands and solvents for lanthanide ions has been obtained: DMF>TBP >NO3-∼H2O >EtOH >dioxane.

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JO - Journal of Inorganic and Nuclear Chemistry

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ER -

The interaction of lanthanide and nitrate ions in solution - II. The relative interaction strength with water and nitrate in organic solvents

Abstract

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