The key role of water in solid-liquid phase transfer-catalysed substitution reactions

Hayder Ali Zahalka; Yoel Sasson

doi:10.1039/C39840001652

The key role of water in solid-liquid phase transfer-catalysed substitution reactions

Hayder Ali Zahalka, Yoel Sasson^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

Traces of water are shown to be essential for substitution reactions catalysed by quaternary ammonium salts; in chloride-formate exchange maximum rate is observed with 0.2% water content of the formate salt, and addition of dehydrating agents reduces the maximum rate by 50%.

Original language	English
Pages (from-to)	1652-1654
Number of pages	3
Journal	Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/C39840001652
State	Published - 1984

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title = "The key role of water in solid-liquid phase transfer-catalysed substitution reactions",

abstract = "Traces of water are shown to be essential for substitution reactions catalysed by quaternary ammonium salts; in chloride-formate exchange maximum rate is observed with 0.2% water content of the formate salt, and addition of dehydrating agents reduces the maximum rate by 50%.",

author = "Zahalka, {Hayder Ali} and Yoel Sasson",

year = "1984",

doi = "10.1039/C39840001652",

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The key role of water in solid-liquid phase transfer-catalysed substitution reactions

Abstract

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