The kinetics and mechanisms of elementary NF2 reactions with O and N atoms

Yu M. Gershenzon; S. D. Il'in; O. P. Kishkovitch; R. T. Malkhasyan; V. B. Rozenshtein; S. Ya Umanskii

doi:10.1002/kin.550150502

The kinetics and mechanisms of elementary NF₂ reactions with O and N atoms

Yu M. Gershenzon^*
, S. D. Il'in
, O. P. Kishkovitch
, R. T. Malkhasyan
, V. B. Rozenshtein
, S. Ya Umanskii

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A combined EPR–LMR spectrometer with a fast‐flow system has been used to investigate the kinetics and mechanisms of NF₂ reactions with O and N atoms at 298 K. The overall rate constants of these reactions are: k₀ = (2.8 ± 0.4) × 10⁻¹¹ cm³/s and k_N = (5.7 ± 0.8) × 10⁻¹¹ cm³/s. The stoichiometry of the reactions with respect to O, N, NF₂, F, and NO has been determined. The statistical theory of bimolecular reactions has been used for interpretation of the results obtained.

Original language	English
Pages (from-to)	399-415
Number of pages	17
Journal	International Journal of Chemical Kinetics
Volume	15
Issue number	5
DOIs	https://doi.org/10.1002/kin.550150502
State	Published - May 1983
Externally published	Yes

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title = "The kinetics and mechanisms of elementary NF2 reactions with O and N atoms",

abstract = "A combined EPR–LMR spectrometer with a fast‐flow system has been used to investigate the kinetics and mechanisms of NF2 reactions with O and N atoms at 298 K. The overall rate constants of these reactions are: k0 = (2.8 ± 0.4) × 10−11 cm3/s and kN = (5.7 ± 0.8) × 10−11 cm3/s. The stoichiometry of the reactions with respect to O, N, NF2, F, and NO has been determined. The statistical theory of bimolecular reactions has been used for interpretation of the results obtained.",

author = "Gershenzon, \{Yu M.\} and Il'in, \{S. D.\} and Kishkovitch, \{O. P.\} and Malkhasyan, \{R. T.\} and Rozenshtein, \{V. B.\} and Umanskii, \{S. Ya\}",

year = "1983",

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doi = "10.1002/kin.550150502",

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T1 - The kinetics and mechanisms of elementary NF2 reactions with O and N atoms

AU - Gershenzon, Yu M.

AU - Il'in, S. D.

AU - Kishkovitch, O. P.

AU - Malkhasyan, R. T.

AU - Rozenshtein, V. B.

AU - Umanskii, S. Ya

PY - 1983/5

Y1 - 1983/5

N2 - A combined EPR–LMR spectrometer with a fast‐flow system has been used to investigate the kinetics and mechanisms of NF2 reactions with O and N atoms at 298 K. The overall rate constants of these reactions are: k0 = (2.8 ± 0.4) × 10−11 cm3/s and kN = (5.7 ± 0.8) × 10−11 cm3/s. The stoichiometry of the reactions with respect to O, N, NF2, F, and NO has been determined. The statistical theory of bimolecular reactions has been used for interpretation of the results obtained.

AB - A combined EPR–LMR spectrometer with a fast‐flow system has been used to investigate the kinetics and mechanisms of NF2 reactions with O and N atoms at 298 K. The overall rate constants of these reactions are: k0 = (2.8 ± 0.4) × 10−11 cm3/s and kN = (5.7 ± 0.8) × 10−11 cm3/s. The stoichiometry of the reactions with respect to O, N, NF2, F, and NO has been determined. The statistical theory of bimolecular reactions has been used for interpretation of the results obtained.

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JO - International Journal of Chemical Kinetics

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IS - 5

ER -

The kinetics and mechanisms of elementary NF₂ reactions with O and N atoms

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