TY - JOUR
T1 - The promoting effect of cupric ions on the ferric ion catalyzed decomposition of hydrogen peroxide
AU - Kremer, Mordechai L.
PY - 1962/8
Y1 - 1962/8
N2 - The effect of Cu2+ ions on the Fe3+ ion catalyzed decomposition of H2O2 was reinvestigated. Deviations from steady state, first order kinetics were observed at a higher [H2O2] in the presence of Cu2+ ions. The results are discussed in terms of the mechanism suggested by Kremer and Stein for the catalytic decomposition of H2O2. The promoting action of Cu2+ is due to its acceleration of the conversion of the primary to the secondary iron (III)-H2O2 complex.
AB - The effect of Cu2+ ions on the Fe3+ ion catalyzed decomposition of H2O2 was reinvestigated. Deviations from steady state, first order kinetics were observed at a higher [H2O2] in the presence of Cu2+ ions. The results are discussed in terms of the mechanism suggested by Kremer and Stein for the catalytic decomposition of H2O2. The promoting action of Cu2+ is due to its acceleration of the conversion of the primary to the secondary iron (III)-H2O2 complex.
UR - http://www.scopus.com/inward/record.url?scp=0038102254&partnerID=8YFLogxK
U2 - 10.1016/0021-9517(62)90063-5
DO - 10.1016/0021-9517(62)90063-5
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AN - SCOPUS:0038102254
SN - 0021-9517
VL - 1
SP - 351
EP - 355
JO - Journal of Catalysis
JF - Journal of Catalysis
IS - 4
ER -