The structure of the 1-1-difluoroethylene radical anion and the factors determining the hyperfine interaction with 19F

L. N. Shchegoleva; I. I. Bilkis; P. V. Schastnev

doi:10.1016/0009-2614(84)80077-9

The structure of the 1-1-difluoroethylene radical anion and the factors determining the hyperfine interaction with ¹⁹F

L. N. Shchegoleva^*, I. I. Bilkis, P. V. Schastnev

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

A structure with a pyramidal -CF₂ group is shown to desribe satisfactorily hyperfine interactions in CH₂CF₂ radical anions within the framework of the INDO method. The factors responsible for the substantial difference in the degree of spin density delocalization on F in CH₂CF₂ and C₂F₄ are analyzed.

Original language	English
Pages (from-to)	348-352
Number of pages	5
Journal	Chemical Physics Letters
Volume	104
Issue number	4
DOIs	https://doi.org/10.1016/0009-2614(84)80077-9
State	Published - 10 Feb 1984
Externally published	Yes

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title = "The structure of the 1-1-difluoroethylene radical anion and the factors determining the hyperfine interaction with 19F",

abstract = "A structure with a pyramidal -CF2 group is shown to desribe satisfactorily hyperfine interactions in CH2CF2 radical anions within the framework of the INDO method. The factors responsible for the substantial difference in the degree of spin density delocalization on F in CH2CF2 and C2F4 are analyzed.",

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AU - Shchegoleva, L. N.

AU - Bilkis, I. I.

AU - Schastnev, P. V.

PY - 1984/2/10

Y1 - 1984/2/10

N2 - A structure with a pyramidal -CF2 group is shown to desribe satisfactorily hyperfine interactions in CH2CF2 radical anions within the framework of the INDO method. The factors responsible for the substantial difference in the degree of spin density delocalization on F in CH2CF2 and C2F4 are analyzed.

AB - A structure with a pyramidal -CF2 group is shown to desribe satisfactorily hyperfine interactions in CH2CF2 radical anions within the framework of the INDO method. The factors responsible for the substantial difference in the degree of spin density delocalization on F in CH2CF2 and C2F4 are analyzed.

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The structure of the 1-1-difluoroethylene radical anion and the factors determining the hyperfine interaction with ¹⁹F

Abstract

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