TY - JOUR
T1 - The structuredness of supercritical water up to 600 °C and 100 MPa as obtained from relative permittivity data
AU - Marcus, Y.
PY - 1999/7
Y1 - 1999/7
N2 - The Kirkwood dipole orientation correlation parameter gK for supercritical water up to T = 600 °C (873 K) and P = 1 kbar (100 MPa) is obtained from the relative permittivity ε (T,P) data of Franck et al., the density ρ (T,P) expression of Duan et al., and estimated infinite frequency permittivity ε∞(T,P) values. Together with first shell coordination numbers Z(T,P) from various sources the mean angle between the nearest neighbor water dipoles is obtained, and its relevance to the structuredness of supercritical water is discussed.
AB - The Kirkwood dipole orientation correlation parameter gK for supercritical water up to T = 600 °C (873 K) and P = 1 kbar (100 MPa) is obtained from the relative permittivity ε (T,P) data of Franck et al., the density ρ (T,P) expression of Duan et al., and estimated infinite frequency permittivity ε∞(T,P) values. Together with first shell coordination numbers Z(T,P) from various sources the mean angle between the nearest neighbor water dipoles is obtained, and its relevance to the structuredness of supercritical water is discussed.
UR - http://www.scopus.com/inward/record.url?scp=0001128238&partnerID=8YFLogxK
U2 - 10.1016/s0167-7322(99)00059-8
DO - 10.1016/s0167-7322(99)00059-8
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AN - SCOPUS:0001128238
SN - 0167-7322
VL - 81
SP - 101
EP - 113
JO - Journal of Molecular Liquids
JF - Journal of Molecular Liquids
IS - 2
ER -