The symmetric broadening of the water relaxation peak in polymer-water mixtures and its relationship to the hydrophilic and hydrophobic properties of polymers

Yaroslav E. Ryabov; Yuri Feldman; Naoki Shinyashiki; Shin Yagihara

doi:10.1063/1.1471551

The symmetric broadening of the water relaxation peak in polymer-water mixtures and its relationship to the hydrophilic and hydrophobic properties of polymers

Yaroslav E. Ryabov^*, Yuri Feldman, Naoki Shinyashiki, Shin Yagihara

^*Corresponding author for this work

The Institute of Applied Physics

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81 Scopus citations

Abstract

The symmetric broadening of the water relaxation peak in polymer-water mixtures and its relationship to the hydrophilic and hydrophobic properties of polymers was presented. The presence of macromolecules in aqueous solutions altered the water structure and water-water interactions. The results showed that the microscopic relaxation time of water molecules in the vicinity of the polymer matrix correlated with the hydrophilicity of the impurities.

Original language	English
Pages (from-to)	8610-8615
Number of pages	6
Journal	Journal of Chemical Physics
Volume	116
Issue number	19
DOIs	https://doi.org/10.1063/1.1471551
State	Published - 15 Mar 2002

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abstract = "The symmetric broadening of the water relaxation peak in polymer-water mixtures and its relationship to the hydrophilic and hydrophobic properties of polymers was presented. The presence of macromolecules in aqueous solutions altered the water structure and water-water interactions. The results showed that the microscopic relaxation time of water molecules in the vicinity of the polymer matrix correlated with the hydrophilicity of the impurities.",

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AU - Ryabov, Yaroslav E.

AU - Feldman, Yuri

AU - Shinyashiki, Naoki

AU - Yagihara, Shin

PY - 2002/3/15

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N2 - The symmetric broadening of the water relaxation peak in polymer-water mixtures and its relationship to the hydrophilic and hydrophobic properties of polymers was presented. The presence of macromolecules in aqueous solutions altered the water structure and water-water interactions. The results showed that the microscopic relaxation time of water molecules in the vicinity of the polymer matrix correlated with the hydrophilicity of the impurities.

AB - The symmetric broadening of the water relaxation peak in polymer-water mixtures and its relationship to the hydrophilic and hydrophobic properties of polymers was presented. The presence of macromolecules in aqueous solutions altered the water structure and water-water interactions. The results showed that the microscopic relaxation time of water molecules in the vicinity of the polymer matrix correlated with the hydrophilicity of the impurities.

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The symmetric broadening of the water relaxation peak in polymer-water mixtures and its relationship to the hydrophilic and hydrophobic properties of polymers

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