TY - JOUR
T1 - The synthesis, structure and properties of the complex between a new donor, 2,3,6,7-tetra(ethyltellura)-tetrathiafulvalene, (TeTeTTF) and tetracyanoquidinomethane (TCNQ)
AU - Aharon-Shalom, Eliezer
AU - Becker, James Y.
AU - Bernstein, Joel
AU - Bittner, Shmuel
AU - Shaik, Sason
PY - 1985/9
Y1 - 1985/9
N2 - The complex between a new donor, 2,3,6,7-tetra(ethyltellura)tetrathiafulvalene (TETeTTF) and TCNQ has been prepared and characterized. Crystals of the complex are trilinic, P1 with a = 9.9245(2) A ̊, b = 11.296 (3)c = 8.461 (2), α = 90.83(6)°, β = 107.8(5), γ = 101.3(5), and Z = 1. The structure was solved by direct methods and refined anisotropically on 2291 reflections to R = 0.051, Rw = 0.072. The molecules are packed in mixed stacks with interplanar spacing of 3.30 Å. Geometric and spectroscopic considerations indicate a degree of charge transfers of ca 0.6. The room temperature conductively (10-2 Ω-1 cm-1 is in the semiconductor region.
AB - The complex between a new donor, 2,3,6,7-tetra(ethyltellura)tetrathiafulvalene (TETeTTF) and TCNQ has been prepared and characterized. Crystals of the complex are trilinic, P1 with a = 9.9245(2) A ̊, b = 11.296 (3)c = 8.461 (2), α = 90.83(6)°, β = 107.8(5), γ = 101.3(5), and Z = 1. The structure was solved by direct methods and refined anisotropically on 2291 reflections to R = 0.051, Rw = 0.072. The molecules are packed in mixed stacks with interplanar spacing of 3.30 Å. Geometric and spectroscopic considerations indicate a degree of charge transfers of ca 0.6. The room temperature conductively (10-2 Ω-1 cm-1 is in the semiconductor region.
UR - http://www.scopus.com/inward/record.url?scp=0022130440&partnerID=8YFLogxK
U2 - 10.1016/0379-6779(85)90018-9
DO - 10.1016/0379-6779(85)90018-9
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AN - SCOPUS:0022130440
SN - 0379-6779
VL - 11
SP - 213
EP - 220
JO - Synthetic Metals
JF - Synthetic Metals
IS - 4-5
ER -