TY - JOUR
T1 - The two luminescent levels of Bi3+ in solids
AU - Boulon, Georges
AU - Jørgensen, Christian K.
AU - Reisfeld, Renata
PY - 1980
Y1 - 1980
N2 - The energy difference between the lowest Bi3+ excited levels may be of three types: ≈ 1200 cm−1 in alkaline earths, which can be interpreted as a nephelauxetic decrease of the separation 4963 cm−1 between 3PO and 3P1 in Bi3+; three times smaller values in many non-cubic oxygen-containing compounds, which may be related to the (3N-6) degrees of vibrational freedom; and below 25 cm−1, representing traps of differing origin.
AB - The energy difference between the lowest Bi3+ excited levels may be of three types: ≈ 1200 cm−1 in alkaline earths, which can be interpreted as a nephelauxetic decrease of the separation 4963 cm−1 between 3PO and 3P1 in Bi3+; three times smaller values in many non-cubic oxygen-containing compounds, which may be related to the (3N-6) degrees of vibrational freedom; and below 25 cm−1, representing traps of differing origin.
UR - http://www.scopus.com/inward/record.url?scp=84877961266&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(80)80456-8
DO - 10.1016/0009-2614(80)80456-8
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AN - SCOPUS:84877961266
SN - 0009-2614
VL - 75
SP - 24
EP - 26
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 1
ER -