The two luminescent levels of Bi3+ in solids

Georges Boulon; Christian K. Jørgensen; Renata Reisfeld

doi:10.1016/0009-2614(80)80456-8

The two luminescent levels of Bi³⁺ in solids

Georges Boulon
, Christian K. Jørgensen
, Renata Reisfeld^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

The energy difference between the lowest Bi³⁺ excited levels may be of three types: ≈ 1200 cm⁻¹ in alkaline earths, which can be interpreted as a nephelauxetic decrease of the separation 4963 cm⁻¹ between ³P_O and ³P₁ in Bi³⁺; three times smaller values in many non-cubic oxygen-containing compounds, which may be related to the (3N-6) degrees of vibrational freedom; and below 25 cm⁻¹, representing traps of differing origin.

Original language	English
Pages (from-to)	24-26
Number of pages	3
Journal	Chemical Physics Letters
Volume	75
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(80)80456-8
State	Published - 1980
Externally published	Yes

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title = "The two luminescent levels of Bi3+ in solids",

abstract = "The energy difference between the lowest Bi3+ excited levels may be of three types: ≈ 1200 cm−1 in alkaline earths, which can be interpreted as a nephelauxetic decrease of the separation 4963 cm−1 between 3PO and 3P1 in Bi3+; three times smaller values in many non-cubic oxygen-containing compounds, which may be related to the (3N-6) degrees of vibrational freedom; and below 25 cm−1, representing traps of differing origin.",

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AU - Boulon, Georges

AU - Jørgensen, Christian K.

AU - Reisfeld, Renata

PY - 1980

Y1 - 1980

N2 - The energy difference between the lowest Bi3+ excited levels may be of three types: ≈ 1200 cm−1 in alkaline earths, which can be interpreted as a nephelauxetic decrease of the separation 4963 cm−1 between 3PO and 3P1 in Bi3+; three times smaller values in many non-cubic oxygen-containing compounds, which may be related to the (3N-6) degrees of vibrational freedom; and below 25 cm−1, representing traps of differing origin.

AB - The energy difference between the lowest Bi3+ excited levels may be of three types: ≈ 1200 cm−1 in alkaline earths, which can be interpreted as a nephelauxetic decrease of the separation 4963 cm−1 between 3PO and 3P1 in Bi3+; three times smaller values in many non-cubic oxygen-containing compounds, which may be related to the (3N-6) degrees of vibrational freedom; and below 25 cm−1, representing traps of differing origin.

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The two luminescent levels of Bi³⁺ in solids

Abstract

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