The viscosity and electrical conductivity of single molten salts

Yizhak Marcus

doi:10.1016/j.cplett.2016.06.020

The viscosity and electrical conductivity of single molten salts

Yizhak Marcus

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In addition to the well-established Arrhenius-type temperature-dependence of the specific and molar conductivities of molten salts, it turns out that they also depend linearly on the molar volumes, in analogy with the behavior of their fluidities. Similar values of the molar volumes representing the immobilization of the ions result from both kinds of flow phenomena. However, the activation energy for the fluidity is some five times larger than for the conductivity.

Original language	English
Pages (from-to)	40-42
Number of pages	3
Journal	Chemical Physics Letters
Volume	659
DOIs	https://doi.org/10.1016/j.cplett.2016.06.020
State	Published - 16 Aug 2016

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© 2016 Elsevier B.V.

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10.1016/j.cplett.2016.06.020

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AB - In addition to the well-established Arrhenius-type temperature-dependence of the specific and molar conductivities of molten salts, it turns out that they also depend linearly on the molar volumes, in analogy with the behavior of their fluidities. Similar values of the molar volumes representing the immobilization of the ions result from both kinds of flow phenomena. However, the activation energy for the fluidity is some five times larger than for the conductivity.

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The viscosity and electrical conductivity of single molten salts

Abstract

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