The Volume Change on Ion-Pairing of Symmetrical Electrolytes

Y. Marcus*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

12 Scopus citations

Abstract

The increase in the standard partial molar volume of a symmetrical electrolyte on ion-pairing, Δ[FORMULA OMITTED]∞, calculated from the experimental association constant at ambient pressure, the isothermal compressibility, the dielectric constant of the solvent and its pressure coefficient, is as good a measure of this quantity as values calculated from more elaborate experimental procedures, such as the pressure coefficient of the association constant or high precision density determinations in dilute solutions.

Original languageEnglish
Pages (from-to)247-251
Number of pages5
JournalZeitschrift fur Naturforschung - Section A Journal of Physical Sciences
Volume38
Issue number2
DOIs
StatePublished - 1 Feb 1983

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