Abstract
The potent odorant β-damascenone was formed directly from 9′-cis-neoxanthin in a model system by peroxyacetic acid oxidation and two-phase thermal degradation without the involvement of enzymatic activity. β-Damascenone formation was heavily dependent on pH (optimum at 5.0) and temperature, occurring over the two sequential phases. The first was incubation with peroxyacetic acid at 60°C for 90 min, and the second was at above 90°C for 20 min. Only traces of β-damascenone were formed on application of only one of the two phases. Formate and citrate solutions produced a much better environment for β-damascenone formation than acetate and phosphate. About 7 μg/L β-damascenone was formed from 5.8 mg/L 9′-cis-neoxanthin under optimal experimental condition. The detailed pathway by which β-damascenone is formed remains to be elucidated.
Original language | English |
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Pages (from-to) | 9199-9206 |
Number of pages | 8 |
Journal | Journal of Agricultural and Food Chemistry |
Volume | 53 |
Issue number | 23 |
DOIs | |
State | Published - 16 Nov 2005 |
Keywords
- β-Damascenone
- 9′-cis-neoxanthin
- Epoxide
- Peroxyacetic acid
- Thermolysis