TY - JOUR
T1 - Thermodynamics of aqueous solutions of noble gases. II. Effect of nonelectrolytes
AU - Ben-Naim, A.
PY - 1965
Y1 - 1965
N2 - The solubility of argon was measured in water and in dilute aqueous solutions of nonelectrolytes: methanol, ethanol, 1-propanol, 1-butanol, glycerol, p-dioxane, glucose, and sucrose. The entropy and enthalpy of solution of argon were calculated from the temperature dependence of the solubility. The difference in these quantities in solution of nonelectrolyte and in pure water is interpreted in terms of a "two-structure" model for liquid water and is attributed to the difference in the degree of crystallinity of the various solvents.
AB - The solubility of argon was measured in water and in dilute aqueous solutions of nonelectrolytes: methanol, ethanol, 1-propanol, 1-butanol, glycerol, p-dioxane, glucose, and sucrose. The entropy and enthalpy of solution of argon were calculated from the temperature dependence of the solubility. The difference in these quantities in solution of nonelectrolyte and in pure water is interpreted in terms of a "two-structure" model for liquid water and is attributed to the difference in the degree of crystallinity of the various solvents.
UR - http://www.scopus.com/inward/record.url?scp=3543071365&partnerID=8YFLogxK
U2 - 10.1021/j100894a004
DO - 10.1021/j100894a004
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AN - SCOPUS:3543071365
SN - 0022-3654
VL - 69
SP - 3245
EP - 3250
JO - Journal of Physical Chemistry
JF - Journal of Physical Chemistry
IS - 10
ER -