TY - JOUR
T1 - Thermodynamics of aqueous solutions of noble gases. III. Effect of electrolytes
AU - Ben-Naim, A.
AU - Egel-Thal, M.
PY - 1965
Y1 - 1965
N2 - The solubility of argon was measured at five temperatures between 5 and 25° in water and in aqueous solutions of electrolytes: LiCl (1 m), NH4Cl (1 m), NaCl (1 m), KCl (1 m), KBr (1 m), NaI (1 m), and KI (1, 2, and 4 m). The entropy and enthalpy of solution of argon were calculated from the temperature dependence of the solubility. The difference in these quantities in solution of electrolytes and in pure water is interpreted in terms of a "two-structure" model for liquid water and is attributed to the decrease of the "degree of crystallinity" of the water caused by the added electrolytes.
AB - The solubility of argon was measured at five temperatures between 5 and 25° in water and in aqueous solutions of electrolytes: LiCl (1 m), NH4Cl (1 m), NaCl (1 m), KCl (1 m), KBr (1 m), NaI (1 m), and KI (1, 2, and 4 m). The entropy and enthalpy of solution of argon were calculated from the temperature dependence of the solubility. The difference in these quantities in solution of electrolytes and in pure water is interpreted in terms of a "two-structure" model for liquid water and is attributed to the decrease of the "degree of crystallinity" of the water caused by the added electrolytes.
UR - http://www.scopus.com/inward/record.url?scp=33947482694&partnerID=8YFLogxK
U2 - 10.1021/j100894a005
DO - 10.1021/j100894a005
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AN - SCOPUS:33947482694
SN - 0022-3654
VL - 69
SP - 3250
EP - 3253
JO - Journal of Physical Chemistry
JF - Journal of Physical Chemistry
IS - 10
ER -