TY - JOUR
T1 - Thermodynamics of Power and Dissipation
AU - Kafri, O.
AU - Levine, R. D.
PY - 1977
Y1 - 1977
N2 - Can one provide a thermodynamic theory for processes which occur with finite rates? We discuss a possible approach based on expressing the first and second laws as rate equations. The result is a first law formulated in terms of power and a second law in terms of rate of energy dissipation. We argue that such an approach introduces a distinction between passive systems which are devoid of memory and cannot store energy and systems with a facility of recall (e.g. a coiled spring). The second possibility, that of systems capable of recall, allows for short term deviations from the overall restrictions imposed by the second law, illustrating the maxim that knowledge is power.
AB - Can one provide a thermodynamic theory for processes which occur with finite rates? We discuss a possible approach based on expressing the first and second laws as rate equations. The result is a first law formulated in terms of power and a second law in terms of rate of energy dissipation. We argue that such an approach introduces a distinction between passive systems which are devoid of memory and cannot store energy and systems with a facility of recall (e.g. a coiled spring). The second possibility, that of systems capable of recall, allows for short term deviations from the overall restrictions imposed by the second law, illustrating the maxim that knowledge is power.
UR - http://www.scopus.com/inward/record.url?scp=84987301325&partnerID=8YFLogxK
U2 - 10.1002/ijch.197700056
DO - 10.1002/ijch.197700056
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AN - SCOPUS:84987301325
SN - 0021-2148
VL - 16
SP - 342
EP - 344
JO - Israel Journal of Chemistry
JF - Israel Journal of Chemistry
IS - 4
ER -