Titanium complexes of chelating dianionic amine bis(phenolate) ligands: An extra donor makes a big difference

Edit Y. Tshuva; Miriam Versano; Israel Goldberg; Moshe Kol; Hana Weitman; Zeev Goldschmidt

doi:10.1016/S1387-7003(99)00096-9

Titanium complexes of chelating dianionic amine bis(phenolate) ligands: An extra donor makes a big difference

Edit Y. Tshuva
, Miriam Versano
, Israel Goldberg
, Moshe Kol^*
, Hana Weitman
, Zeev Goldschmidt

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

98 Scopus citations

Abstract

Two dianionic amine bis(phenolate) ligands are introduced and their reactions with titanium tetra(iso-propoxide) studied; ligand 1 having a single N-donor group leads exclusively to a homoleptic Lig₂Ti type complex whereas ligand 3 having an additional N-donor on a side arm leads exclusively to a LigTi(OPrⁱ)₂ type complex.

Original language	English
Pages (from-to)	371-373
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	2
Issue number	8
DOIs	https://doi.org/10.1016/S1387-7003(99)00096-9
State	Published - 1 Aug 1999
Externally published	Yes

Bibliographical note

Funding Information:
This research was supported in part by the Israel Science foundation founded by the Israel Academy of Sciences and Humanities. We thank Sima Alfi (BIU) for technical assistance.

Keywords

Crystal structures
Octahedral geometry
Phenolate ligands
Titanium complexes

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10.1016/S1387-7003(99)00096-9

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title = "Titanium complexes of chelating dianionic amine bis(phenolate) ligands: An extra donor makes a big difference",

abstract = "Two dianionic amine bis(phenolate) ligands are introduced and their reactions with titanium tetra(iso-propoxide) studied; ligand 1 having a single N-donor group leads exclusively to a homoleptic Lig2Ti type complex whereas ligand 3 having an additional N-donor on a side arm leads exclusively to a LigTi(OPri)2 type complex.",

keywords = "Crystal structures, Octahedral geometry, Phenolate ligands, Titanium complexes",

author = "Tshuva, \{Edit Y.\} and Miriam Versano and Israel Goldberg and Moshe Kol and Hana Weitman and Zeev Goldschmidt",

note = "Funding Information: This research was supported in part by the Israel Science foundation founded by the Israel Academy of Sciences and Humanities. We thank Sima Alfi (BIU) for technical assistance.",

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doi = "10.1016/S1387-7003(99)00096-9",

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T2 - An extra donor makes a big difference

AU - Tshuva, Edit Y.

AU - Versano, Miriam

AU - Goldberg, Israel

AU - Kol, Moshe

AU - Weitman, Hana

AU - Goldschmidt, Zeev

N1 - Funding Information: This research was supported in part by the Israel Science foundation founded by the Israel Academy of Sciences and Humanities. We thank Sima Alfi (BIU) for technical assistance.

PY - 1999/8/1

Y1 - 1999/8/1

N2 - Two dianionic amine bis(phenolate) ligands are introduced and their reactions with titanium tetra(iso-propoxide) studied; ligand 1 having a single N-donor group leads exclusively to a homoleptic Lig2Ti type complex whereas ligand 3 having an additional N-donor on a side arm leads exclusively to a LigTi(OPri)2 type complex.

AB - Two dianionic amine bis(phenolate) ligands are introduced and their reactions with titanium tetra(iso-propoxide) studied; ligand 1 having a single N-donor group leads exclusively to a homoleptic Lig2Ti type complex whereas ligand 3 having an additional N-donor on a side arm leads exclusively to a LigTi(OPri)2 type complex.

KW - Crystal structures

KW - Octahedral geometry

KW - Phenolate ligands

KW - Titanium complexes

UR - https://www.scopus.com/pages/publications/0033424396

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JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 8

ER -

Titanium complexes of chelating dianionic amine bis(phenolate) ligands: An extra donor makes a big difference

Abstract

Bibliographical note

Keywords

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