Trans-spanned palladium catalyst for mild and efficient amination of aryl halides with benzophenone imine

Olga Grossman; Karola Rueck-Braun; Dmitri Gelman

doi:10.1055/s-2008-1032142

Trans-spanned palladium catalyst for mild and efficient amination of aryl halides with benzophenone imine

Olga Grossman, Karola Rueck-Braun, Dmitri Gelman^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

A new protocol for palladium-catalyzed Buchwald-Hartwig amination of aryl chlorides and bromides with benzophenone imine as ammonia surrogate is described. The suggested reaction conditions are mild and may therefore be applied to a variety of sensitive starting materials.

Original language	English
Pages (from-to)	537-542
Number of pages	6
Journal	Synthesis
Issue number	4
DOIs	https://doi.org/10.1055/s-2008-1032142
State	Published - 15 Feb 2008

Keywords

Aminations
Palladium-catalyzed
Trans-spanning ligands
Triptycene

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10.1055/s-2008-1032142

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title = "Trans-spanned palladium catalyst for mild and efficient amination of aryl halides with benzophenone imine",

abstract = "A new protocol for palladium-catalyzed Buchwald-Hartwig amination of aryl chlorides and bromides with benzophenone imine as ammonia surrogate is described. The suggested reaction conditions are mild and may therefore be applied to a variety of sensitive starting materials.",

keywords = "Aminations, Palladium-catalyzed, Trans-spanning ligands, Triptycene",

author = "Olga Grossman and Karola Rueck-Braun and Dmitri Gelman",

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AU - Grossman, Olga

AU - Rueck-Braun, Karola

AU - Gelman, Dmitri

PY - 2008/2/15

Y1 - 2008/2/15

N2 - A new protocol for palladium-catalyzed Buchwald-Hartwig amination of aryl chlorides and bromides with benzophenone imine as ammonia surrogate is described. The suggested reaction conditions are mild and may therefore be applied to a variety of sensitive starting materials.

AB - A new protocol for palladium-catalyzed Buchwald-Hartwig amination of aryl chlorides and bromides with benzophenone imine as ammonia surrogate is described. The suggested reaction conditions are mild and may therefore be applied to a variety of sensitive starting materials.

KW - Aminations

KW - Palladium-catalyzed

KW - Trans-spanning ligands

KW - Triptycene

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AN - SCOPUS:39749177076

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JO - Synthesis

JF - Synthesis

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ER -

Trans-spanned palladium catalyst for mild and efficient amination of aryl halides with benzophenone imine

Abstract

Keywords

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