Transfer hydrogenolysis of aryl bromides by sodium formate and palladium-phosphine catalyst under phase transfer conditions

Raphael Bar; Yoel Sasson; Jochanan Blum

doi:10.1016/0304-5102(82)85005-0

Transfer hydrogenolysis of aryl bromides by sodium formate and palladium-phosphine catalyst under phase transfer conditions

Raphael Bar, Yoel Sasson^*, Jochanan Blum

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Palladium-triphenylphospine-catalyzed transfer hydrogenolysis of aryl bromides by aqueous sodium formate in a two-liquid phase system is described. Tetrahexylammonium hydrogen sulfate proved to be the best phase transfer catalyst in this system. Substitution of the H₂O by D₂O led to the selective transformation of the aryl bromides to monodeuterated products.

Original language	English
Pages (from-to)	175-180
Number of pages	6
Journal	Journal of Molecular Catalysis
Volume	16
Issue number	2
DOIs	https://doi.org/10.1016/0304-5102(82)85005-0
State	Published - Aug 1982

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title = "Transfer hydrogenolysis of aryl bromides by sodium formate and palladium-phosphine catalyst under phase transfer conditions",

abstract = "Palladium-triphenylphospine-catalyzed transfer hydrogenolysis of aryl bromides by aqueous sodium formate in a two-liquid phase system is described. Tetrahexylammonium hydrogen sulfate proved to be the best phase transfer catalyst in this system. Substitution of the H2O by D2O led to the selective transformation of the aryl bromides to monodeuterated products.",

author = "Raphael Bar and Yoel Sasson and Jochanan Blum",

year = "1982",

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T1 - Transfer hydrogenolysis of aryl bromides by sodium formate and palladium-phosphine catalyst under phase transfer conditions

AU - Bar, Raphael

AU - Sasson, Yoel

AU - Blum, Jochanan

PY - 1982/8

Y1 - 1982/8

N2 - Palladium-triphenylphospine-catalyzed transfer hydrogenolysis of aryl bromides by aqueous sodium formate in a two-liquid phase system is described. Tetrahexylammonium hydrogen sulfate proved to be the best phase transfer catalyst in this system. Substitution of the H2O by D2O led to the selective transformation of the aryl bromides to monodeuterated products.

AB - Palladium-triphenylphospine-catalyzed transfer hydrogenolysis of aryl bromides by aqueous sodium formate in a two-liquid phase system is described. Tetrahexylammonium hydrogen sulfate proved to be the best phase transfer catalyst in this system. Substitution of the H2O by D2O led to the selective transformation of the aryl bromides to monodeuterated products.

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JO - Journal of Molecular Catalysis

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ER -

Transfer hydrogenolysis of aryl bromides by sodium formate and palladium-phosphine catalyst under phase transfer conditions

Abstract

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