TY - JOUR
T1 - Transformation of π-conjugated macrocycles
T2 - from furanophanes to napthalenophanes
AU - Rajagopal, Shinaj K.
AU - Dishi, Or
AU - Bogoslavsky, Benny
AU - Gidron, Ori
N1 - Publisher Copyright:
© 2022 The Royal Society of Chemistry.
PY - 2022/11/16
Y1 - 2022/11/16
N2 - Applying sequential Diels-Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in the solid state, inclusion of solvent molecules within the macrocycle, and low reduction potentials.
AB - Applying sequential Diels-Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in the solid state, inclusion of solvent molecules within the macrocycle, and low reduction potentials.
UR - http://www.scopus.com/inward/record.url?scp=85142751571&partnerID=8YFLogxK
U2 - 10.1039/d2cc05434e
DO - 10.1039/d2cc05434e
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C2 - 36412186
AN - SCOPUS:85142751571
SN - 1359-7345
VL - 58
SP - 13652
EP - 13655
JO - Chemical Communications
JF - Chemical Communications
IS - 98
ER -