Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes

Shinaj K. Rajagopal; Or Dishi; Benny Bogoslavsky; Ori Gidron

doi:10.1039/d2cc05434e

Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes

Shinaj K. Rajagopal
, Or Dishi
, Benny Bogoslavsky
, Ori Gidron^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Applying sequential Diels-Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in the solid state, inclusion of solvent molecules within the macrocycle, and low reduction potentials.

Original language	English
Pages (from-to)	13652-13655
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	98
DOIs	https://doi.org/10.1039/d2cc05434e
State	Published - 16 Nov 2022

Bibliographical note

Publisher Copyright:
© 2022 The Royal Society of Chemistry.

Access to Document

10.1039/d2cc05434e

Cite this

@article{5af976252ef14b58abcbb362a0854e8e,

title = "Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes",

abstract = "Applying sequential Diels-Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in the solid state, inclusion of solvent molecules within the macrocycle, and low reduction potentials.",

author = "Rajagopal, \{Shinaj K.\} and Or Dishi and Benny Bogoslavsky and Ori Gidron",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

year = "2022",

month = nov,

day = "16",

doi = "10.1039/d2cc05434e",

language = "אנגלית",

volume = "58",

pages = "13652--13655",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "98",

}

TY - JOUR

T1 - Transformation of π-conjugated macrocycles

T2 - from furanophanes to napthalenophanes

AU - Rajagopal, Shinaj K.

AU - Dishi, Or

AU - Bogoslavsky, Benny

AU - Gidron, Ori

PY - 2022/11/16

Y1 - 2022/11/16

N2 - Applying sequential Diels-Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in the solid state, inclusion of solvent molecules within the macrocycle, and low reduction potentials.

AB - Applying sequential Diels-Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in the solid state, inclusion of solvent molecules within the macrocycle, and low reduction potentials.

UR - https://www.scopus.com/pages/publications/85142751571

U2 - 10.1039/d2cc05434e

DO - 10.1039/d2cc05434e

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

C2 - 36412186

AN - SCOPUS:85142751571

SN - 1359-7345

VL - 58

SP - 13652

EP - 13655

JO - Chemical Communications

JF - Chemical Communications

IS - 98

ER -

Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Cite this