Transition metal-catalyzed transfer reduction of saturated aldehydes and ketones by sodium formate under phase transfer conditions

Raphael Bar; Yoel Sasson; Jochanan Blum

doi:10.1016/0304-5102(84)85105-6

Transition metal-catalyzed transfer reduction of saturated aldehydes and ketones by sodium formate under phase transfer conditions

Raphael Bar^*, Yoel Sasson, Jochanan Blum

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Saturated aldehydes and ketones were shown to undergo transfer hydrogenation by sodium formate under phase transfer conditions in the presence of Aliquat-336. While RuCl₂(PPh₃)₃ was found to be the best catalyst for aldehyde reduction, a 1:10 mixture of RhCl(PPh₃)₃ and PPh₃ showed the highest activity in the transformation of ketones.

Original language	English
Pages (from-to)	327-332
Number of pages	6
Journal	Journal of Molecular Catalysis
Volume	26
Issue number	3
DOIs	https://doi.org/10.1016/0304-5102(84)85105-6
State	Published - Oct 1984

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title = "Transition metal-catalyzed transfer reduction of saturated aldehydes and ketones by sodium formate under phase transfer conditions",

abstract = "Saturated aldehydes and ketones were shown to undergo transfer hydrogenation by sodium formate under phase transfer conditions in the presence of Aliquat-336. While RuCl2(PPh3)3 was found to be the best catalyst for aldehyde reduction, a 1:10 mixture of RhCl(PPh3)3 and PPh3 showed the highest activity in the transformation of ketones.",

author = "Raphael Bar and Yoel Sasson and Jochanan Blum",

year = "1984",

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T1 - Transition metal-catalyzed transfer reduction of saturated aldehydes and ketones by sodium formate under phase transfer conditions

AU - Bar, Raphael

AU - Sasson, Yoel

AU - Blum, Jochanan

PY - 1984/10

Y1 - 1984/10

N2 - Saturated aldehydes and ketones were shown to undergo transfer hydrogenation by sodium formate under phase transfer conditions in the presence of Aliquat-336. While RuCl2(PPh3)3 was found to be the best catalyst for aldehyde reduction, a 1:10 mixture of RhCl(PPh3)3 and PPh3 showed the highest activity in the transformation of ketones.

AB - Saturated aldehydes and ketones were shown to undergo transfer hydrogenation by sodium formate under phase transfer conditions in the presence of Aliquat-336. While RuCl2(PPh3)3 was found to be the best catalyst for aldehyde reduction, a 1:10 mixture of RhCl(PPh3)3 and PPh3 showed the highest activity in the transformation of ketones.

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ER -

Transition metal-catalyzed transfer reduction of saturated aldehydes and ketones by sodium formate under phase transfer conditions

Abstract

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