TY - JOUR
T1 - Transition state geometries and the magnitudes of SN2 barriers. A theoretical study
AU - Shaik, Sason S.
AU - Schlegel, H. Bernhard
AU - Wolfe, Saul
PY - 1988
Y1 - 1988
N2 - For SN2 reactions of the type Y- + MeX → YMe + X-, there exist extended linear correlations between (i) the magnitude of the central barrier and the percentage elongation of the C-X bond in the transition state; (ii) the looseness of the transition state and the sum of the forward and reverse central barriers.
AB - For SN2 reactions of the type Y- + MeX → YMe + X-, there exist extended linear correlations between (i) the magnitude of the central barrier and the percentage elongation of the C-X bond in the transition state; (ii) the looseness of the transition state and the sum of the forward and reverse central barriers.
UR - http://www.scopus.com/inward/record.url?scp=37049089061&partnerID=8YFLogxK
U2 - 10.1039/C39880001322
DO - 10.1039/C39880001322
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AN - SCOPUS:37049089061
SN - 0022-4936
SP - 1322
EP - 1323
JO - Chemical Communications
JF - Chemical Communications
IS - 19
ER -