Transition-strength fluctuations and the onset of chaotic motion

The maximum-entropy formalism is used to characterize the fluctuations in transition strengths for a bound quantum-mechanical system. In the chaotic limit only one, ever present, sum rule is required as a constraint. The resulting distribution is that of Porter and Thomas, which can also be derived from random-matrix theory. For nonchaotic systems the distribution of transition strengths has a lower entropy. A possible additional constraint, operative during the onset of chaos, is proposed. The distribution of maximal entropy subject to both constraints accords with computed intensities in a system of two degrees of freedom.