Transmethylation reactions of sodium trimethylsilylpropionate and sodium 2,2-dimethyl-2-silapentane-5-sulfonate with Hg(II) species

J. D. Nies; J. M. Bellama; Nava Ben-Zvi

doi:10.1016/S0020-1693(00)86399-9

Transmethylation reactions of sodium trimethylsilylpropionate and sodium 2,2-dimethyl-2-silapentane-5-sulfonate with Hg(II) species

J. D. Nies, J. M. Bellama^*, Nava Ben-Zvi

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The effects of temperature, pCl and concentration on the rate and extent of silicon carbon bond cleavage by mercury(II) species were studied by ¹H NMR. Transmethylation reactions were found to be first order with respect to each reactant and second order overall. The rate of reaction is strongly dependent upon the nature of the mercury(II) electrophile. A mechanism consistent with the kinetic data is proposed.

Original language	English
Pages (from-to)	1-5
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	118
Issue number	1
DOIs	https://doi.org/10.1016/S0020-1693(00)86399-9
State	Published - 1 Aug 1986
Externally published	Yes

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abstract = "The effects of temperature, pCl and concentration on the rate and extent of silicon carbon bond cleavage by mercury(II) species were studied by 1H NMR. Transmethylation reactions were found to be first order with respect to each reactant and second order overall. The rate of reaction is strongly dependent upon the nature of the mercury(II) electrophile. A mechanism consistent with the kinetic data is proposed.",

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AU - Bellama, J. M.

AU - Ben-Zvi, Nava

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N2 - The effects of temperature, pCl and concentration on the rate and extent of silicon carbon bond cleavage by mercury(II) species were studied by 1H NMR. Transmethylation reactions were found to be first order with respect to each reactant and second order overall. The rate of reaction is strongly dependent upon the nature of the mercury(II) electrophile. A mechanism consistent with the kinetic data is proposed.

AB - The effects of temperature, pCl and concentration on the rate and extent of silicon carbon bond cleavage by mercury(II) species were studied by 1H NMR. Transmethylation reactions were found to be first order with respect to each reactant and second order overall. The rate of reaction is strongly dependent upon the nature of the mercury(II) electrophile. A mechanism consistent with the kinetic data is proposed.

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Transmethylation reactions of sodium trimethylsilylpropionate and sodium 2,2-dimethyl-2-silapentane-5-sulfonate with Hg(II) species

Abstract

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