Trivalent chromium in the solid solution system CrxMo1-xO2 (x ≤ 0.5)

Y. Shimony; L. Ben-Dor

doi:10.1016/0025-5408(80)90124-5

Trivalent chromium in the solid solution system Cr_xMo_1-xO₂ (x ≤ 0.5)

Y. Shimony, L. Ben-Dor^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

the solid solution system Cr_xMo_1-xO₂ for x ≤ 0.5 was investigated. The following three phases were identified from x-ray powder diffraction analyses: monoclinic distorted rutile (CrMoO₄) for 0.36 ≤ x ≤ 0.5, tetragonal rutile for 0.12 ≤ x < 0.36 and monoclinic (MoO₂) for 0 ≤ x < 0.12. From magnetic data it was shown that throughout the whole range the magnetic ion was trivalent chromium (d³) and the pentavalent molybdenum (d¹) due to its metallic Mo-Mo interactions does not contribute to the magnetic moment.

Original language	English
Pages (from-to)	227-232
Number of pages	6
Journal	Materials Research Bulletin
Volume	15
Issue number	2
DOIs	https://doi.org/10.1016/0025-5408(80)90124-5
State	Published - Feb 1980

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title = "Trivalent chromium in the solid solution system CrxMo1-xO2 (x ≤ 0.5)",

abstract = "the solid solution system CrxMo1-xO2 for x ≤ 0.5 was investigated. The following three phases were identified from x-ray powder diffraction analyses: monoclinic distorted rutile (CrMoO4) for 0.36 ≤ x ≤ 0.5, tetragonal rutile for 0.12 ≤ x < 0.36 and monoclinic (MoO2) for 0 ≤ x < 0.12. From magnetic data it was shown that throughout the whole range the magnetic ion was trivalent chromium (d3) and the pentavalent molybdenum (d1) due to its metallic Mo-Mo interactions does not contribute to the magnetic moment.",

author = "Y. Shimony and L. Ben-Dor",

year = "1980",

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doi = "10.1016/0025-5408(80)90124-5",

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AU - Shimony, Y.

AU - Ben-Dor, L.

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N2 - the solid solution system CrxMo1-xO2 for x ≤ 0.5 was investigated. The following three phases were identified from x-ray powder diffraction analyses: monoclinic distorted rutile (CrMoO4) for 0.36 ≤ x ≤ 0.5, tetragonal rutile for 0.12 ≤ x < 0.36 and monoclinic (MoO2) for 0 ≤ x < 0.12. From magnetic data it was shown that throughout the whole range the magnetic ion was trivalent chromium (d3) and the pentavalent molybdenum (d1) due to its metallic Mo-Mo interactions does not contribute to the magnetic moment.

AB - the solid solution system CrxMo1-xO2 for x ≤ 0.5 was investigated. The following three phases were identified from x-ray powder diffraction analyses: monoclinic distorted rutile (CrMoO4) for 0.36 ≤ x ≤ 0.5, tetragonal rutile for 0.12 ≤ x < 0.36 and monoclinic (MoO2) for 0 ≤ x < 0.12. From magnetic data it was shown that throughout the whole range the magnetic ion was trivalent chromium (d3) and the pentavalent molybdenum (d1) due to its metallic Mo-Mo interactions does not contribute to the magnetic moment.

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Trivalent chromium in the solid solution system Cr_xMo_1-xO₂ (x ≤ 0.5)

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