Understanding the distribution of chlorine in perovskite solar cells via X-ray fluorescence microscopy

Yanqi Luo; Shany Gamliel; Sally Nijem; Sigalit Aharon; Martin Holt; Benjamin Stripe; Volker Rose; Mariana I. Bertoni; Lioz Etgar; David P. Fenning

doi:10.1109/PVSC.2017.8366121

Understanding the distribution of chlorine in perovskite solar cells via X-ray fluorescence microscopy

Yanqi Luo
, Shany Gamliel
, Sally Nijem
, Sigalit Aharon
, Martin Holt
, Benjamin Stripe
, Volker Rose
, Mariana I. Bertoni
, Lioz Etgar
, David P. Fenning

Institute of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

1 Scopus citations

Abstract

Spatial heterogeneities in the chemical makeup of thin film photovoltaic devices are pivotal in determining device efficiency. In this study, the presence of chlorine is identified in perovskite films synthesized with Cl-containing precursors by means of nanoprobe X-ray fluorescence (Nano-XRF). Additionally, a spatial variation in the Cl incorporation is observed within a given film, and the standard deviation of Cl:I ratio across the film is large. Using Nano-XRF, the Cl incorporation in methylammonium lead iodide perovskite films can be manipulated by precursor stoichiometry ratio.

Original language	English
Title of host publication	2017 IEEE 44th Photovoltaic Specialist Conference, PVSC 2017
Publisher	Institute of Electrical and Electronics Engineers Inc.
Pages	730-734
Number of pages	5
ISBN (Electronic)	9781509056057
DOIs	https://doi.org/10.1109/PVSC.2017.8366121
State	Published - 2017
Event	44th IEEE Photovoltaic Specialist Conference, PVSC 2017 - Washington, United States Duration: 25 Jun 2017 → 30 Jun 2017

Publication series

Name	2017 IEEE 44th Photovoltaic Specialist Conference, PVSC 2017

Conference

Conference	44th IEEE Photovoltaic Specialist Conference, PVSC 2017
Country/Territory	United States
City	Washington
Period	25/06/17 → 30/06/17

Bibliographical note

Publisher Copyright:
© 2017 IEEE.

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Cl containing precursors
Elemental distribution
Nano-XRF
Perovskite solar cells
Synchrotron based technique

Access to Document

10.1109/PVSC.2017.8366121

Cite this

Luo, Y., Gamliel, S., Nijem, S., Aharon, S., Holt, M., Stripe, B., Rose, V., Bertoni, M. I., Etgar, L., & Fenning, D. P. (2017). Understanding the distribution of chlorine in perovskite solar cells via X-ray fluorescence microscopy. In 2017 IEEE 44th Photovoltaic Specialist Conference, PVSC 2017 (pp. 730-734). (2017 IEEE 44th Photovoltaic Specialist Conference, PVSC 2017). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/PVSC.2017.8366121

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title = "Understanding the distribution of chlorine in perovskite solar cells via X-ray fluorescence microscopy",

abstract = "Spatial heterogeneities in the chemical makeup of thin film photovoltaic devices are pivotal in determining device efficiency. In this study, the presence of chlorine is identified in perovskite films synthesized with Cl-containing precursors by means of nanoprobe X-ray fluorescence (Nano-XRF). Additionally, a spatial variation in the Cl incorporation is observed within a given film, and the standard deviation of Cl:I ratio across the film is large. Using Nano-XRF, the Cl incorporation in methylammonium lead iodide perovskite films can be manipulated by precursor stoichiometry ratio.",

keywords = "Cl containing precursors, Elemental distribution, Nano-XRF, Perovskite solar cells, Synchrotron based technique",

author = "Yanqi Luo and Shany Gamliel and Sally Nijem and Sigalit Aharon and Martin Holt and Benjamin Stripe and Volker Rose and Bertoni, \{Mariana I.\} and Lioz Etgar and Fenning, \{David P.\}",

note = "Publisher Copyright: {\textcopyright} 2017 IEEE.; 44th IEEE Photovoltaic Specialist Conference, PVSC 2017 ; Conference date: 25-06-2017 Through 30-06-2017",

year = "2017",

doi = "10.1109/PVSC.2017.8366121",

language = "אנגלית",

series = "2017 IEEE 44th Photovoltaic Specialist Conference, PVSC 2017",

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Luo, Y, Gamliel, S, Nijem, S, Aharon, S, Holt, M, Stripe, B, Rose, V, Bertoni, MI, Etgar, L & Fenning, DP 2017, Understanding the distribution of chlorine in perovskite solar cells via X-ray fluorescence microscopy. in 2017 IEEE 44th Photovoltaic Specialist Conference, PVSC 2017. 2017 IEEE 44th Photovoltaic Specialist Conference, PVSC 2017, Institute of Electrical and Electronics Engineers Inc., pp. 730-734, 44th IEEE Photovoltaic Specialist Conference, PVSC 2017, Washington, United States, 25/06/17. https://doi.org/10.1109/PVSC.2017.8366121

Understanding the distribution of chlorine in perovskite solar cells via X-ray fluorescence microscopy. / Luo, Yanqi; Gamliel, Shany; Nijem, Sally et al.
2017 IEEE 44th Photovoltaic Specialist Conference, PVSC 2017. Institute of Electrical and Electronics Engineers Inc., 2017. p. 730-734 (2017 IEEE 44th Photovoltaic Specialist Conference, PVSC 2017).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AU - Holt, Martin

AU - Stripe, Benjamin

AU - Rose, Volker

AU - Bertoni, Mariana I.

AU - Etgar, Lioz

AU - Fenning, David P.

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AB - Spatial heterogeneities in the chemical makeup of thin film photovoltaic devices are pivotal in determining device efficiency. In this study, the presence of chlorine is identified in perovskite films synthesized with Cl-containing precursors by means of nanoprobe X-ray fluorescence (Nano-XRF). Additionally, a spatial variation in the Cl incorporation is observed within a given film, and the standard deviation of Cl:I ratio across the film is large. Using Nano-XRF, the Cl incorporation in methylammonium lead iodide perovskite films can be manipulated by precursor stoichiometry ratio.

KW - Cl containing precursors

KW - Elemental distribution

KW - Nano-XRF

KW - Perovskite solar cells

KW - Synchrotron based technique

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PB - Institute of Electrical and Electronics Engineers Inc.

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ER -

Luo Y, Gamliel S, Nijem S, Aharon S, Holt M, Stripe B et al. Understanding the distribution of chlorine in perovskite solar cells via X-ray fluorescence microscopy. In 2017 IEEE 44th Photovoltaic Specialist Conference, PVSC 2017. Institute of Electrical and Electronics Engineers Inc. 2017. p. 730-734. (2017 IEEE 44th Photovoltaic Specialist Conference, PVSC 2017). doi: 10.1109/PVSC.2017.8366121

Understanding the distribution of chlorine in perovskite solar cells via X-ray fluorescence microscopy

Abstract

Publication series

Conference

Bibliographical note

UN SDGs

Keywords

Access to Document

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Cite this