Unexpected luminescence of Cr5+ and Cr3+ ions in ZrSiO4 zircon crystals

M. Gaft; G. Boulon; G. Panczer; Y. Guyot; R. Reisfeld; S. Votyakov; G. Bulka

doi:10.1016/S0022-2313(99)00562-1

Unexpected luminescence of Cr⁵⁺ and Cr³⁺ ions in ZrSiO₄ zircon crystals

M. Gaft^*
, G. Boulon
, G. Panczer
, Y. Guyot
, R. Reisfeld
, S. Votyakov
, G. Bulka

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Conference article › peer-review

30 Scopus citations

Abstract

Luminescence, decay-times and EPR spectroscopy of Cr-doped ZrSiO₄ show the presence of both Cr³⁺ and Cr⁵⁺ active centers, which can be connected with Zr⁴⁺ and Si⁴⁺ adjacent two-cation replacement. Cr⁵⁺ emission occurs within a similar spectral range as for Cr⁴⁺ and hence confusion is possible.

Original language	English
Pages (from-to)	1118-1121
Number of pages	4
Journal	Journal of Luminescence
Volume	87
DOIs	https://doi.org/10.1016/S0022-2313(99)00562-1
State	Published - May 2000
Event	International Conference on Luminescence and Optical Spectroscopy of Condensed Matter (ICL'99) - Osaka, Jpn Duration: 23 Aug 1999 → 27 Aug 1999

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title = "Unexpected luminescence of Cr5+ and Cr3+ ions in ZrSiO4 zircon crystals",

abstract = "Luminescence, decay-times and EPR spectroscopy of Cr-doped ZrSiO4 show the presence of both Cr3+ and Cr5+ active centers, which can be connected with Zr4+ and Si4+ adjacent two-cation replacement. Cr5+ emission occurs within a similar spectral range as for Cr4+ and hence confusion is possible.",

author = "M. Gaft and G. Boulon and G. Panczer and Y. Guyot and R. Reisfeld and S. Votyakov and G. Bulka",

year = "2000",

month = may,

doi = "10.1016/S0022-2313(99)00562-1",

language = "אנגלית",

volume = "87",

pages = "1118--1121",

journal = "Journal of Luminescence",

issn = "0022-2313",

publisher = "Elsevier B.V.",

note = "International Conference on Luminescence and Optical Spectroscopy of Condensed Matter (ICL'99) ; Conference date: 23-08-1999 Through 27-08-1999",

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TY - JOUR

T1 - Unexpected luminescence of Cr5+ and Cr3+ ions in ZrSiO4 zircon crystals

AU - Gaft, M.

AU - Boulon, G.

AU - Panczer, G.

AU - Guyot, Y.

AU - Reisfeld, R.

AU - Votyakov, S.

AU - Bulka, G.

PY - 2000/5

Y1 - 2000/5

N2 - Luminescence, decay-times and EPR spectroscopy of Cr-doped ZrSiO4 show the presence of both Cr3+ and Cr5+ active centers, which can be connected with Zr4+ and Si4+ adjacent two-cation replacement. Cr5+ emission occurs within a similar spectral range as for Cr4+ and hence confusion is possible.

AB - Luminescence, decay-times and EPR spectroscopy of Cr-doped ZrSiO4 show the presence of both Cr3+ and Cr5+ active centers, which can be connected with Zr4+ and Si4+ adjacent two-cation replacement. Cr5+ emission occurs within a similar spectral range as for Cr4+ and hence confusion is possible.

UR - https://www.scopus.com/pages/publications/0033727633

U2 - 10.1016/S0022-2313(99)00562-1

DO - 10.1016/S0022-2313(99)00562-1

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AN - SCOPUS:0033727633

SN - 0022-2313

VL - 87

SP - 1118

EP - 1121

JO - Journal of Luminescence

JF - Journal of Luminescence

T2 - International Conference on Luminescence and Optical Spectroscopy of Condensed Matter (ICL'99)

Y2 - 23 August 1999 through 27 August 1999

ER -

Unexpected luminescence of Cr⁵⁺ and Cr³⁺ ions in ZrSiO₄ zircon crystals

Abstract

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