TY - JOUR
T1 - Unsymmetrical 1,1-bisboryl species
T2 - Valuable building blocks in synthesis
AU - Babu, K. Naresh
AU - Massarwe, Fedaa
AU - Reddy, Reddy Rajasekhar
AU - Eghbarieh, Nadim
AU - Jakob, Manuella
AU - Masarwa, Ahmad
N1 - Publisher Copyright:
© 2020 by the authors.
PY - 2020/2/20
Y1 - 2020/2/20
N2 - Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.
AB - Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.
KW - 1,1-bis(boryl)alkanes and alkenes
KW - Bismetallated organic compounds
KW - Chemoselective transformations
KW - Suzuki-Miyaura cross-coupling
UR - http://www.scopus.com/inward/record.url?scp=85079886823&partnerID=8YFLogxK
U2 - 10.3390/molecules25040959
DO - 10.3390/molecules25040959
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C2 - 32093409
AN - SCOPUS:85079886823
SN - 1420-3049
VL - 25
JO - Molecules
JF - Molecules
IS - 4
M1 - 959
ER -