Unsymmetrical 1,1-bisboryl species: Valuable building blocks in synthesis

K. Naresh Babu, Fedaa Massarwe, Reddy Rajasekhar Reddy, Nadim Eghbarieh, Manuella Jakob, Ahmad Masarwa*

*Corresponding author for this work

Research output: Contribution to journalReview articlepeer-review

21 Scopus citations

Abstract

Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.

Original languageAmerican English
Article number959
JournalMolecules
Volume25
Issue number4
DOIs
StatePublished - 20 Feb 2020

Bibliographical note

Publisher Copyright:
© 2020 by the authors.

Keywords

  • 1,1-bis(boryl)alkanes and alkenes
  • Bismetallated organic compounds
  • Chemoselective transformations
  • Suzuki-Miyaura cross-coupling

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