Unsymmetrical 1,1-bisboryl species: Valuable building blocks in synthesis

K. Naresh Babu; Fedaa Massarwe; Reddy Rajasekhar Reddy; Nadim Eghbarieh; Manuella Jakob; Ahmad Masarwa

doi:10.3390/molecules25040959

Unsymmetrical 1,1-bisboryl species: Valuable building blocks in synthesis

K. Naresh Babu, Fedaa Massarwe, Reddy Rajasekhar Reddy, Nadim Eghbarieh, Manuella Jakob, Ahmad Masarwa^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Review article › peer-review

15 Scopus citations

Abstract

Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.

Original language	American English
Article number	959
Journal	Molecules
Volume	25
Issue number	4
DOIs	https://doi.org/10.3390/molecules25040959
State	Published - 20 Feb 2020

Bibliographical note

Funding Information:
Acknowledgments: A.M. is grateful to the Azrieli Foundation for the receipt of an Azrieli Fellowship. K.N.B., N.M., F.M., and R.R.R. are thankful to HUJI for a research fellowship.

Publisher Copyright:
© 2020 by the authors.

Keywords

1,1-bis(boryl)alkanes and alkenes
Bismetallated organic compounds
Chemoselective transformations
Suzuki-Miyaura cross-coupling

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10.3390/molecules25040959

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title = "Unsymmetrical 1,1-bisboryl species: Valuable building blocks in synthesis",

abstract = "Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.",

keywords = "1,1-bis(boryl)alkanes and alkenes, Bismetallated organic compounds, Chemoselective transformations, Suzuki-Miyaura cross-coupling",

author = "Babu, {K. Naresh} and Fedaa Massarwe and Reddy, {Reddy Rajasekhar} and Nadim Eghbarieh and Manuella Jakob and Ahmad Masarwa",

note = "Funding Information: Acknowledgments: A.M. is grateful to the Azrieli Foundation for the receipt of an Azrieli Fellowship. K.N.B., N.M., F.M., and R.R.R. are thankful to HUJI for a research fellowship. Publisher Copyright: {\textcopyright} 2020 by the authors.",

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doi = "10.3390/molecules25040959",

language = "American English",

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T2 - Valuable building blocks in synthesis

AU - Babu, K. Naresh

AU - Massarwe, Fedaa

AU - Reddy, Reddy Rajasekhar

AU - Eghbarieh, Nadim

AU - Jakob, Manuella

AU - Masarwa, Ahmad

N1 - Funding Information: Acknowledgments: A.M. is grateful to the Azrieli Foundation for the receipt of an Azrieli Fellowship. K.N.B., N.M., F.M., and R.R.R. are thankful to HUJI for a research fellowship. Publisher Copyright: © 2020 by the authors.

PY - 2020/2/20

Y1 - 2020/2/20

N2 - Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.

AB - Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.

KW - 1,1-bis(boryl)alkanes and alkenes

KW - Bismetallated organic compounds

KW - Chemoselective transformations

KW - Suzuki-Miyaura cross-coupling

UR - http://www.scopus.com/inward/record.url?scp=85079886823&partnerID=8YFLogxK

U2 - 10.3390/molecules25040959

DO - 10.3390/molecules25040959

M3 - Review article

C2 - 32093409

AN - SCOPUS:85079886823

SN - 1420-3049

VL - 25

JO - Molecules

JF - Molecules

IS - 4

M1 - 959

ER -

Unsymmetrical 1,1-bisboryl species: Valuable building blocks in synthesis

Abstract

Bibliographical note

Keywords

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