Unsymmetrical 1,1-bisboryl species: Valuable building blocks in synthesis

K. Naresh Babu; Fedaa Massarwe; Reddy Rajasekhar Reddy; Nadim Eghbarieh; Manuella Jakob; Ahmad Masarwa

doi:10.3390/molecules25040959

Unsymmetrical 1,1-bisboryl species: Valuable building blocks in synthesis

K. Naresh Babu
, Fedaa Massarwe
, Reddy Rajasekhar Reddy
, Nadim Eghbarieh
, Manuella Jakob
, Ahmad Masarwa^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Review article › peer-review

28 Scopus citations

Abstract

Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.

Original language	English
Article number	959
Journal	Molecules
Volume	25
Issue number	4
DOIs	https://doi.org/10.3390/molecules25040959
State	Published - 20 Feb 2020

Bibliographical note

Publisher Copyright:
© 2020 by the authors.

Keywords

1,1-bis(boryl)alkanes and alkenes
Bismetallated organic compounds
Chemoselective transformations
Suzuki-Miyaura cross-coupling

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10.3390/molecules25040959

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abstract = "Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.",

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AU - Babu, K. Naresh

AU - Massarwe, Fedaa

AU - Reddy, Reddy Rajasekhar

AU - Eghbarieh, Nadim

AU - Jakob, Manuella

AU - Masarwa, Ahmad

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N2 - Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.

AB - Unsymmetrical 1,1-bis(boryl)alkanes and alkenes are organo-bismetallic equivalents, which are synthetically important because they allow for sequential selective transformations of C-B bonds. We reviewed the synthesis and chemical reactivity of 1,1-bis(boryl)alkanes and alkenes to provide information for the synthetic community. In the first part of this review, we disclose the synthesis and chemical reactivity of unsymmetrical 1,1-bisborylalkanes. In the second part, we describe the synthesis and chemical reactivity of unsymmetrical 1,1-bis(boryl)alkenes.

KW - 1,1-bis(boryl)alkanes and alkenes

KW - Bismetallated organic compounds

KW - Chemoselective transformations

KW - Suzuki-Miyaura cross-coupling

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Unsymmetrical 1,1-bisboryl species: Valuable building blocks in synthesis

Abstract

Bibliographical note

Keywords

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