TY - JOUR
T1 - Use of chemical probes for the characterization of solvent mixtures. Part 1. Completely non-aqueous mixtures
AU - Marcus, Yizhak
PY - 1994
Y1 - 1994
N2 - The use of chemical probes for the characterization of chemical properties (polarity, hydrogen bonding ability) is explored for solvent mixtures not involving water as a component. Preferential solvation is more important in such mixtures than in those that contain water. This implies that contrary to common practice, polarity indices etc. obtained in the mixtures with a given probe may not be generally valid for the solvation of other solutes. Still, approximate values of these properties can be obtained by judicious use of such probes.
AB - The use of chemical probes for the characterization of chemical properties (polarity, hydrogen bonding ability) is explored for solvent mixtures not involving water as a component. Preferential solvation is more important in such mixtures than in those that contain water. This implies that contrary to common practice, polarity indices etc. obtained in the mixtures with a given probe may not be generally valid for the solvation of other solutes. Still, approximate values of these properties can be obtained by judicious use of such probes.
UR - http://www.scopus.com/inward/record.url?scp=37049076260&partnerID=8YFLogxK
U2 - 10.1039/p29940001015
DO - 10.1039/p29940001015
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AN - SCOPUS:37049076260
SN - 1472-779X
SP - 1015
EP - 1021
JO - Journal of the Chemical Society, Perkin Transactions 2
JF - Journal of the Chemical Society, Perkin Transactions 2
IS - 5
ER -