Versatile deuterium exchange and isomerization of hydrocarbons via phase transfer catalysis

Itamar Willner; Marc Halpern; Mordecai Rabinovitz

doi:10.1039/C39780000155

Versatile deuterium exchange and isomerization of hydrocarbons via phase transfer catalysis

Itamar Willner
, Marc Halpern
, Mordecai Rabinovitz^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The complete deuteriation of indene (1) at C(1) and C(3) and fluorene (2) at C(9), and the allylic isomerization of 1-methylindene (3) to 3-methylindene (6) are reported; phase transfer catalysis is shown to be an easy and efficient method for deuterium exchange and isomerization of acidic hydrocarbons.

Original language	English
Pages (from-to)	155-156
Number of pages	2
Journal	Journal of the Chemical Society D: Chemical Communications
Issue number	4
DOIs	https://doi.org/10.1039/C39780000155
State	Published - 1978

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title = "Versatile deuterium exchange and isomerization of hydrocarbons via phase transfer catalysis",

abstract = "The complete deuteriation of indene (1) at C(1) and C(3) and fluorene (2) at C(9), and the allylic isomerization of 1-methylindene (3) to 3-methylindene (6) are reported; phase transfer catalysis is shown to be an easy and efficient method for deuterium exchange and isomerization of acidic hydrocarbons.",

author = "Itamar Willner and Marc Halpern and Mordecai Rabinovitz",

year = "1978",

doi = "10.1039/C39780000155",

language = "אנגלית",

pages = "155--156",

journal = "Journal of the Chemical Society D: Chemical Communications",

issn = "0022-4936",

publisher = "Chemical Society",

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T1 - Versatile deuterium exchange and isomerization of hydrocarbons via phase transfer catalysis

AU - Willner, Itamar

AU - Halpern, Marc

AU - Rabinovitz, Mordecai

PY - 1978

Y1 - 1978

N2 - The complete deuteriation of indene (1) at C(1) and C(3) and fluorene (2) at C(9), and the allylic isomerization of 1-methylindene (3) to 3-methylindene (6) are reported; phase transfer catalysis is shown to be an easy and efficient method for deuterium exchange and isomerization of acidic hydrocarbons.

AB - The complete deuteriation of indene (1) at C(1) and C(3) and fluorene (2) at C(9), and the allylic isomerization of 1-methylindene (3) to 3-methylindene (6) are reported; phase transfer catalysis is shown to be an easy and efficient method for deuterium exchange and isomerization of acidic hydrocarbons.

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AN - SCOPUS:37049109664

SN - 0022-4936

SP - 155

EP - 156

JO - Journal of the Chemical Society D: Chemical Communications

JF - Journal of the Chemical Society D: Chemical Communications

IS - 4

ER -

Versatile deuterium exchange and isomerization of hydrocarbons via phase transfer catalysis

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