Vibrational and rotational energy disposal in the H + D2 reaction at 1.3 eV: Surprisal analysis of experiments and computations

E. Zamir; R. D. Levine; R. B. Bernstein

doi:10.1016/0009-2614(84)85117-9

Vibrational and rotational energy disposal in the H + D₂ reaction at 1.3 eV: Surprisal analysis of experiments and computations

E. Zamir^*
, R. D. Levine
, R. B. Bernstein

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

19 Scopus citations

Abstract

Recent independent experimental determinations, by Zare and Valentini and their co-workers, of the HD product state distribution are consistent with a common set of surprisal parameters: λ_ν = 2 and θ_R in the range 3-5. Analysis of the computational results of Blais and Truhlar suggests that a somewhat larger fraction of the available energy is channeled into rotation and that theorientation of the emergent HD molecules is constrained.

Original language	English
Pages (from-to)	217-221
Number of pages	5
Journal	Chemical Physics Letters
Volume	107
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(84)85117-9
State	Published - 1 Jun 1984

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abstract = "Recent independent experimental determinations, by Zare and Valentini and their co-workers, of the HD product state distribution are consistent with a common set of surprisal parameters: λν = 2 and θR in the range 3-5. Analysis of the computational results of Blais and Truhlar suggests that a somewhat larger fraction of the available energy is channeled into rotation and that theorientation of the emergent HD molecules is constrained.",

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AU - Bernstein, R. B.

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AB - Recent independent experimental determinations, by Zare and Valentini and their co-workers, of the HD product state distribution are consistent with a common set of surprisal parameters: λν = 2 and θR in the range 3-5. Analysis of the computational results of Blais and Truhlar suggests that a somewhat larger fraction of the available energy is channeled into rotation and that theorientation of the emergent HD molecules is constrained.

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Vibrational and rotational energy disposal in the H + D₂ reaction at 1.3 eV: Surprisal analysis of experiments and computations

Abstract

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