TY - JOUR
T1 - Vibrational dephasing of I3- in cooled ethanol solutions - where is the inhomogeneity?
AU - Wang, Zhaohui
AU - Wasserman, Thierry
AU - Gershgoren, Erez
AU - Ruhman, Sanford
PY - 2000/6
Y1 - 2000/6
N2 - The vibrational dephasing of triiodide ions is studied in ethanol solutions, at temperatures ranging from room temperature to 80 K. The dynamics of dephasing is demonstrated to be homogeneous throughout that range, and not to be dominated by population relaxation. The very mild temperature dependence of the dephasing rate, and the lack of observable inhomogeneous broadening, even in the solid, are discussed.
AB - The vibrational dephasing of triiodide ions is studied in ethanol solutions, at temperatures ranging from room temperature to 80 K. The dynamics of dephasing is demonstrated to be homogeneous throughout that range, and not to be dominated by population relaxation. The very mild temperature dependence of the dephasing rate, and the lack of observable inhomogeneous broadening, even in the solid, are discussed.
UR - http://www.scopus.com/inward/record.url?scp=0034206365&partnerID=8YFLogxK
U2 - 10.1016/S0167-7322(99)00144-0
DO - 10.1016/S0167-7322(99)00144-0
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AN - SCOPUS:0034206365
SN - 0167-7322
VL - 86
SP - 229
EP - 236
JO - Journal of Molecular Liquids
JF - Journal of Molecular Liquids
IS - 1
ER -