Vibrational-rotational-translational energy exchange in molecule-surface collisions

A. O. Bawagan; L. H. Beard; R. B. Gerber; D. J. Kouri

doi:10.1016/0009-2614(81)80359-4

Vibrational-rotational-translational energy exchange in molecule-surface collisions

A. O. Bawagan^*
, L. H. Beard
, R. B. Gerber
, D. J. Kouri

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Vibrational deactivation probabilities are calculated for N₂,O₂, Cl₂, I₂ in collision with smooth surfaces, using the recent DWES model. It is found that molecular rotation dominates over translation in receiving the vibrational energy released, even for the heaviest diatomics.

Original language	English
Pages (from-to)	339-342
Number of pages	4
Journal	Chemical Physics Letters
Volume	84
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(81)80359-4
State	Published - 1981

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@article{3c93db0eddfb458cac82df44e7ef16f8,

title = "Vibrational-rotational-translational energy exchange in molecule-surface collisions",

abstract = "Vibrational deactivation probabilities are calculated for N2,O2, Cl2, I2 in collision with smooth surfaces, using the recent DWES model. It is found that molecular rotation dominates over translation in receiving the vibrational energy released, even for the heaviest diatomics.",

author = "Bawagan, \{A. O.\} and Beard, \{L. H.\} and Gerber, \{R. B.\} and Kouri, \{D. J.\}",

year = "1981",

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AU - Bawagan, A. O.

AU - Beard, L. H.

AU - Gerber, R. B.

AU - Kouri, D. J.

PY - 1981

Y1 - 1981

N2 - Vibrational deactivation probabilities are calculated for N2,O2, Cl2, I2 in collision with smooth surfaces, using the recent DWES model. It is found that molecular rotation dominates over translation in receiving the vibrational energy released, even for the heaviest diatomics.

AB - Vibrational deactivation probabilities are calculated for N2,O2, Cl2, I2 in collision with smooth surfaces, using the recent DWES model. It is found that molecular rotation dominates over translation in receiving the vibrational energy released, even for the heaviest diatomics.

UR - https://www.scopus.com/pages/publications/3743096867

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

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Vibrational-rotational-translational energy exchange in molecule-surface collisions

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