Abstract
The water-structural contributions to the entropies and heat capacities of hydration of over 120 ions and the viscosity B-coefficients of nearly 80 aqueous ions are tabulated and correlated. B-coefficients for many more ions are predicted from this relationship and from their dependence on ionic size and charge. The structural entropies determine a unique scale of water structure making and breaking by the ions.
| Original language | English |
|---|---|
| Pages (from-to) | 831-848 |
| Number of pages | 18 |
| Journal | Journal of Solution Chemistry |
| Volume | 23 |
| Issue number | 7 |
| DOIs | |
| State | Published - Jul 1994 |
Keywords
- Aqueous ions
- entropy of hydration
- heat capacity of hydration
- viscosity B-coefficients
- water structure
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