Visible-light-driven Cr(vi) reduction by ferrocene-integrated conjugated porous polymers via dual catalytic routes

Yan Wang; Weijie Zhang; Yumin Yang; Juntao Tang; Chunyue Pan; You Nian Liu; Raed Abu-Reziq; Guipeng Yu

doi:10.1039/d1cc01079d

Visible-light-driven Cr(vi) reduction by ferrocene-integrated conjugated porous polymers via dual catalytic routes

Yan Wang
, Weijie Zhang
, Yumin Yang
, Juntao Tang^*
, Chunyue Pan
, You Nian Liu
, Raed Abu-Reziq
, Guipeng Yu^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Conjugated porous polymers with rapid separation of photogenerated charges and multiple catalytic pathways remain a great challenge. Herein, two ferrocene-based polymers (Fc-CPPs) with high charge separation efficiency and unique dual catalytic routes for Cr(vi) reduction were developed. They exhibited an excellent efficiency, with almost 99% of Cr(vi) readily converted to Cr(iii) under 15 min of visible light illumination (λ > 420 nm).

Original language	English
Pages (from-to)	4886-4889
Number of pages	4
Journal	Chemical Communications
Volume	57
Issue number	40
DOIs	https://doi.org/10.1039/d1cc01079d
State	Published - 18 May 2021

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© 2021 The Royal Society of Chemistry.

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abstract = "Conjugated porous polymers with rapid separation of photogenerated charges and multiple catalytic pathways remain a great challenge. Herein, two ferrocene-based polymers (Fc-CPPs) with high charge separation efficiency and unique dual catalytic routes for Cr(vi) reduction were developed. They exhibited an excellent efficiency, with almost 99\% of Cr(vi) readily converted to Cr(iii) under 15 min of visible light illumination (λ > 420 nm).",

author = "Yan Wang and Weijie Zhang and Yumin Yang and Juntao Tang and Chunyue Pan and Liu, \{You Nian\} and Raed Abu-Reziq and Guipeng Yu",

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AU - Wang, Yan

AU - Zhang, Weijie

AU - Yang, Yumin

AU - Tang, Juntao

AU - Pan, Chunyue

AU - Liu, You Nian

AU - Abu-Reziq, Raed

AU - Yu, Guipeng

PY - 2021/5/18

Y1 - 2021/5/18

N2 - Conjugated porous polymers with rapid separation of photogenerated charges and multiple catalytic pathways remain a great challenge. Herein, two ferrocene-based polymers (Fc-CPPs) with high charge separation efficiency and unique dual catalytic routes for Cr(vi) reduction were developed. They exhibited an excellent efficiency, with almost 99% of Cr(vi) readily converted to Cr(iii) under 15 min of visible light illumination (λ > 420 nm).

AB - Conjugated porous polymers with rapid separation of photogenerated charges and multiple catalytic pathways remain a great challenge. Herein, two ferrocene-based polymers (Fc-CPPs) with high charge separation efficiency and unique dual catalytic routes for Cr(vi) reduction were developed. They exhibited an excellent efficiency, with almost 99% of Cr(vi) readily converted to Cr(iii) under 15 min of visible light illumination (λ > 420 nm).

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ER -

Visible-light-driven Cr(vi) reduction by ferrocene-integrated conjugated porous polymers via dual catalytic routes

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