Volumetric Behaviour of Room Temperature Ionic Liquids

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Abstract

The volumetric behaviour of room temperature ionic liquids (RTILs) depends on their measured densities. The isobaric expansibilities and isothermal compressibilities depend on the availability of densities as functions of the temperature and the pressure. In view of the proliferation of data for various combinations of cations and anions that have been used for RTILs, only the most popular ones are dealt with here: those based on imidazolium, pyridinium, and quaternary ammonium and phosphonium salts. The most popular anions are tetrafluoroborate, hexafluorophosphate, bis(trifluorosulfonyl)imide, alkylsulfate, small inorganic anions, and carboxylate anions.

Original languageEnglish
Title of host publicationVolume Properties
Subtitle of host publicationLiquids, Solutions and Vapours
PublisherRSC
Pages512-525
Number of pages14
ISBN (Electronic)9781782627043
ISBN (Print)1849738998, 9781782623434
DOIs
StatePublished - 1 Jan 2014

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry 2015. All rights reserved.

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