Weak- and strong-coupling electrostatic interactions between asymmetrically charged planar surfaces

M. Kanduč; M. Trulsson; A. Naji; Y. Burak; J. Forsman; R. Podgornik

doi:10.1103/PhysRevE.78.061105

Weak- and strong-coupling electrostatic interactions between asymmetrically charged planar surfaces

M. Kanduč^*
, M. Trulsson
, A. Naji
, Y. Burak
, J. Forsman
, R. Podgornik

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

49 Scopus citations

Abstract

We compare weak- and strong-coupling theory of counterion-mediated electrostatic interactions between two asymmetrically charged plates with extensive Monte Carlo simulations. Analytical results in both weak- and strong-coupling limits compare excellently with simulations in their respective regimes of validity. The system shows a surprisingly rich structure in terms of interactions between the surfaces as well as fundamental qualitative differences in behavior in the weak- and the strong-coupling limits.

Original language	English
Article number	061105
Journal	Physical Review E
Volume	78
Issue number	6
DOIs	https://doi.org/10.1103/PhysRevE.78.061105
State	Published - 1 Dec 2008
Externally published	Yes

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10.1103/PhysRevE.78.061105

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abstract = "We compare weak- and strong-coupling theory of counterion-mediated electrostatic interactions between two asymmetrically charged plates with extensive Monte Carlo simulations. Analytical results in both weak- and strong-coupling limits compare excellently with simulations in their respective regimes of validity. The system shows a surprisingly rich structure in terms of interactions between the surfaces as well as fundamental qualitative differences in behavior in the weak- and the strong-coupling limits.",

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AU - Kanduč, M.

AU - Trulsson, M.

AU - Naji, A.

AU - Burak, Y.

AU - Forsman, J.

AU - Podgornik, R.

PY - 2008/12/1

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N2 - We compare weak- and strong-coupling theory of counterion-mediated electrostatic interactions between two asymmetrically charged plates with extensive Monte Carlo simulations. Analytical results in both weak- and strong-coupling limits compare excellently with simulations in their respective regimes of validity. The system shows a surprisingly rich structure in terms of interactions between the surfaces as well as fundamental qualitative differences in behavior in the weak- and the strong-coupling limits.

AB - We compare weak- and strong-coupling theory of counterion-mediated electrostatic interactions between two asymmetrically charged plates with extensive Monte Carlo simulations. Analytical results in both weak- and strong-coupling limits compare excellently with simulations in their respective regimes of validity. The system shows a surprisingly rich structure in terms of interactions between the surfaces as well as fundamental qualitative differences in behavior in the weak- and the strong-coupling limits.

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Weak- and strong-coupling electrostatic interactions between asymmetrically charged planar surfaces

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