X-ray crystal and molecular structure of the complex between dibenzo-14-crown-4 and LiSCN

G. Shoham*, W. N. Lipscomb, U. Olsher

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

47 Scopus citations

Abstract

The crystal structure of the title compound shows that in the complex the Li+ cation is penta-co-ordinated to the 4 ethereal oxygens and to the N of the SCN - anion, in a nearly square pyramidal geometry, where Li is 0.79 Å out of the plane of the oxygens; the average Li-O distance is 2.04 Å and Li-N is 1.96 Å.

Original languageAmerican English
Pages (from-to)208-209
Number of pages2
JournalChemical Communications
Issue number5
DOIs
StatePublished - 1983
Externally publishedYes

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