Zirconocene-mediated selective c-c bond cleavage of strained carbocycles: Scope and mechanism

Keyphrases

• Bond Cleavage 100%
• Carbocycles 100%
• Zirconocene 100%
• DFT Calculations 50%
• Spiro 50%
• Easy Access 50%
• Stereoselectivity 50%
• Good Yield 50%
• Propylene 50%
• Polysubstituted 50%
• Cyclopropanols 50%
• Alkylidenecyclopropanes 50%
• Excellent Selectivity 50%
• Methyl Ethers 50%
• Organometallic Intermediate 50%
• Isotopic Labeling Experiments 50%
• Chemoselectivity 50%
• Three-membered Rings 50%
• Microreversibility 50%
• Pentane 50%

Chemistry

• Density Functional Theory 100%
• Chemoselectivity 100%
• Metallocene 100%
• Cyclopropane 100%
• Stereoselectivity 100%
• Zirconocene 100%
• Pentane 100%